Crystal Structure of Bis(1-butyl-1-methypyrrolidinium) Perthiodicarbonate Complex
Noël Pinaud,
Yann Danten,
Mathieu Marchivie,
Marcel Besnard,
Isabel Cabaço,
Jean Guillon
Affiliations
Noël Pinaud
ISM—CNRS UMR 5255, University of Bordeaux, 351 Cours de la Libération, F-33405 Talence, France
Yann Danten
GSM—ISM—CNRS UMR 5255, University of Bordeaux, 351 Cours de la Libération, F-33405 Talence, France
Mathieu Marchivie
CNRS, Bordeaux INP, ICMCB, UMR 5026, University of Bordeaux, 87 Avenue du Docteur Schweitzer, F-33608 Pessac, France
Marcel Besnard
GSM—ISM—CNRS UMR 5255, University of Bordeaux, 351 Cours de la Libération, F-33405 Talence, France
Isabel Cabaço
CeFEMA, Centro de Física e Engenharia de Materiais Avançados, Departamento de Física, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal
Jean Guillon
ARNA Laboratory, INSERM U12132-UMR CNRS 5320, Faculty of Pharmacy, University of Bordeaux, 146 Rue Léo Saignat, F-33076 Bordeaux, France
Bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate was obtained by the reaction of carbon disulfide with 1-butyl-1-methypyrrolidinium acetate ([BmPyrro][Ac]) in the liquid phase. Structural characterization of this original complex was achieved by single-crystal X-ray diffraction (SCXRD) analysis. The asymmetric unit of the title compound, C2S6·2C9H20N, consisted of two crystallographically 1-methyl-1-butyl pyrrolidinium cations and one perthiodicarbonate anion. The complex C2S6·2C9H20N crystallized in the monoclinic space group, C 2/c, and possessed the following cell parameters: a = 16.0970(10) Å, b = 14.7140(9) Å, c = 12.3280(8) Å, α = 90°, β = 112.3730(12)°, γ = 90°, V = 2700.11 Å3, and Z = 8, Z’ = 0.5.
