Molecules
(Jul 2015)
Synthesis of Chiral 1,4,2-Oxazaphosphepines
Oscar Salgado-Escobar,
Leticia Chavelas-Hernández,
Blanca E. Domínguez-Mendoza,
Irma Linzaga-Elizalde,
Mario Ordoñez
Affiliations
Oscar Salgado-Escobar
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
Leticia Chavelas-Hernández
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
Blanca E. Domínguez-Mendoza
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
Irma Linzaga-Elizalde
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
Mario Ordoñez
Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62209 Cuernavaca, Morelos, Mexico
DOI
https://doi.org/10.3390/molecules200813794
Journal volume & issue
Vol. 20,
no. 8
pp.
13794
– 13813
Abstract
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Synthesis and structural characterization of 1,4,2-oxazaphosphepines is described. The 1,4,2-oxazaphosphepines were obtained from reaction of chiral 1,3-benzoxazines with dichlorophenylphosphine or triethyl phosphite. The configuration of some of these compounds was stablished by X-ray analysis.
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