Acta Crystallographica Section E (Feb 2014)

1-Azaniumylcyclobutane-1-carboxylate monohydrate

  • Ray J. Butcher,
  • Greg Brewer,
  • Aaron S. Burton,
  • Jason P. Dworkin

DOI
https://doi.org/10.1107/S1600536813033217
Journal volume & issue
Vol. 70, no. 2
pp. o217 – o218

Abstract

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In the title compound, C5H9NO2·H2O, the amino acid is in the usual zwitterionic form involving the α-carboxylate group. The cyclobutane backbone of the amino acid is disordered over two conformations, with occupancies of 0.882 (7) and 0.118 (7). In the crystal, N—H...O and O—H...O hydrogen bonds link the zwitterions [with the water molecule involved as both acceptor (with the NH3+) and donor (through a single carboxylate O from two different aminocyclobutane carboxylate moities)], resulting in a two-dimensional layered structure lying parallel to (100).