Nonlinear optical absorption and optical limiting of magnetic iron oxide nanomaterials

Abstract

Abstract Integration of nanoparticles into polymeric materials enhances the optical properties and stability of the formed nano-composite materials. In this work, magnetic iron oxide nanoparticles Fe3O4NPs were prepared via chemical coprecipitation. In addition, it is polymerized in a host of polyvinylpyrrolidone PVP. The prepared iron oxide nano-size was about 14.0 nm as confirmed by Transmission Electron Microscopy, A vibrating sample magnetometer VSM studies showed Fe3O4NPs possess superparamagnetic behavior. Energy-dispersive X-ray spectroscopy, and X-ray diffraction confirmed the structure and composition of Fe3O4NPs. Open aperture Z-scan and optical limiting experiments were carried out at nanosecond pulses of wavelength 532 nm. The nonlinear absorption coefficients were calculated for the colloidal and polymeric iron oxide. Fe3O4NPs polymeric film exhibits enhanced nonlinear optical properties NLO, and superior optical limiting properties compared to Fe3O4NPs colloidal solution. That makes Fe3O4 nanocomposites a promising candidate for optical limiting applications.

Keywords

• Iron oxide nanoparticle
• Optical properties
• Z-scan
• Polymeric film
• Structural properties
• Magnetic nanoparticles