Nature Communications (Dec 2019)
Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex
- Wei Huang,
- Shuqi Wu,
- Xiangwei Gu,
- Yao Li,
- Atsushi Okazawa,
- Norimichi Kojima,
- Shinya Hayami,
- Michael L. Baker,
- Peter Bencok,
- Mariko Noguchi,
- Yuji Miyazaki,
- Motohiro Nakano,
- Takumi Nakanishi,
- Shinji Kanegawa,
- Yuji Inagaki,
- Tatsuya Kawae,
- Gui-Lin Zhuang,
- Yoshihito Shiota,
- Kazunari Yoshizawa,
- Dayu Wu,
- Osamu Sato
Affiliations
- Wei Huang
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University
- Shuqi Wu
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- Xiangwei Gu
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University
- Yao Li
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University
- Atsushi Okazawa
- Department of Basic Science, Graduation School of Arts and Sciences, The University of Tokyo
- Norimichi Kojima
- Toyota Physical and Chemical Research Institute
- Shinya Hayami
- Department of Chemistry, Graduate School of Science and Technology and Institute of Pulsed Power Science (IPPS), Kumamoto University
- Michael L. Baker
- The School of Chemistry, The University of Manchester
- Peter Bencok
- Diamond Light Source, Science Division
- Mariko Noguchi
- Research Center for Structural Thermodynamics, Graduate School of Science, Osaka University
- Yuji Miyazaki
- Research Center for Structural Thermodynamics, Graduate School of Science, Osaka University
- Motohiro Nakano
- Research Center for Structural Thermodynamics, Graduate School of Science, Osaka University
- Takumi Nakanishi
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- Shinji Kanegawa
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- Yuji Inagaki
- Department of Applied Quantum Physics, Faculty of Engineering, Kyushu University
- Tatsuya Kawae
- Department of Applied Quantum Physics, Faculty of Engineering, Kyushu University
- Gui-Lin Zhuang
- Institute of Industrial Catalysis, College of Chemical Engineering, State Key Lab Breeding Base of Green-Chemical Synthesis Technology, Zhejiang University of Technology
- Yoshihito Shiota
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- Kazunari Yoshizawa
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- Dayu Wu
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University
- Osamu Sato
- Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University
- DOI
- https://doi.org/10.1038/s41467-019-13279-y
- Journal volume & issue
-
Vol. 10,
no. 1
pp. 1 – 9
Abstract
Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure
