IUCrData (Feb 2017)

1-[(1R,2S,4R,7S)-3,3-Dichloro-4,11,11-trimethyltricyclo[5.4.0.02,4]undecan-7-yl]ethanone

  • Ahmed Benharref,
  • Lahcen El Ammari,
  • Mohamed Saadi,
  • Mustapha Ait Elhad,
  • Abdelouahd Oukhrib,
  • Moha Berraho

DOI
https://doi.org/10.1107/S2414314617001985
Journal volume & issue
Vol. 2, no. 2
p. x170198

Abstract

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The title compound, C16H24Cl2O, crystallizes with two independent molecules in the asymmetric unit. Each molecule is built up from two fused six-membered rings, one of which is fused to a three-membered ring. The two molecules differ essentially in the orientation of two of the methyl groups. The dihedral angles between the mean planes through the two six-membered rings are 57.98 (13) and 55.29 (13)°. The molecular conformation is stabilized by intramolecular C—H...Cl hydrogen bonds.

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