A visible-light-active ellagic acid-based titanium-oxo cluster for room temperature chemiresistive sensing

Abstract

In this study, we synthesized a visible-light-active titanium-oxo cluster (TOC), i.e., [(CH3)2NH2]+2·[Ti4L2(OiPr)10]2− (1), based on ellagic acid (H4L). The molecular structure of 1 was determined using single-crystal X-ray diffraction, revealing a cyclodextrin-like tetramer formed by four Ti4 clusters and dimethylamine cations. Owing to its effective ligand-to-metal charge transfer, 1 exhibited good visible-light absorption ability and photocurrent response, as confirmed by ultraviolet–visible (UV–vis) spectroscopy and photoelectric testing. Structurally, the large number of uncoordinated oxygen sites in 1 serve not only as assembly sites but also as active sites for NO2 detection. Moreover, 1 exhibited high NO2 response and excellent selectivity under visible-light irradiation at room temperature. This research provides the first exploration of TOCs in gas sensing applications, expanding their potential beyond traditional uses.

Keywords

• titanium-oxo clusters
• visible-light-active
• ellagic acid
• chemiresistive sensing