Selectivity of Relative Humidity Using a CP Based on S-Block Metal Ions
Amalia García-García,
Víctor Toral,
José F. Quílez del Moral,
Alberto Galisteo Pretel,
Diego P. Morales,
Alfonso Salinas-Castillo,
Javier Cepeda,
Duane Choquesillo-Lazarte,
Marco Bobinger,
José F. Salmerón,
Almudena Rivadeneyra,
Antonio Rodríguez-Diéguez
Affiliations
Amalia García-García
Department of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain
Víctor Toral
Pervasive Electronics Advanced Research Laboratory (PEARL), Department Electronics and Computer Technology, University of Granada, 18071 Granada, Spain
José F. Quílez del Moral
Department of Organic Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain
Alberto Galisteo Pretel
Department of Organic Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain
Diego P. Morales
Pervasive Electronics Advanced Research Laboratory (PEARL), Department Electronics and Computer Technology, University of Granada, 18071 Granada, Spain
Alfonso Salinas-Castillo
Department of Analytical Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain
Javier Cepeda
Department of Applied Chemistry, Faculty of Chemistry, University of the Basque Country (UPV/EHU), 20018 Donostia-San Sebastián, Spain
Duane Choquesillo-Lazarte
Laboratorio de Estudios Cristalográficos, IACT, CSIC-Universidad de Granada, Avda. de las Palmeras 4, Armilla, 18100 Granada, Spain
Marco Bobinger
Institute for Nanoelectronics, Technical University of Munich, 80333 Munich, Germany
José F. Salmerón
Pervasive Electronics Advanced Research Laboratory (PEARL), Department Electronics and Computer Technology, University of Granada, 18071 Granada, Spain
Almudena Rivadeneyra
Pervasive Electronics Advanced Research Laboratory (PEARL), Department Electronics and Computer Technology, University of Granada, 18071 Granada, Spain
Antonio Rodríguez-Diéguez
Department of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain
Herein, we present the syntheses of a novel coordination polymer (CP) based on the perylene-3,4,9,10-tetracarboxylate (pery) linkers and sodium metal ions. We have chosen sodium metal center with the aim of surmising the effect that the modification of the metal ion may have on the relative humidity (RH) experimental measurements of the material. We confirm the role of the ions in the functionalization of the deposited layer by modifying their selectivity towards moisture content, paving the way to the generation of sensitive and selective chemical sensors.
