Recovery of Mg from H₂SO₄ Leaching Solution of Serpentine to Precipitation of High-Purity Mg(OH)₂ and 4MgCO₃·Mg(OH)₂·4H₂O

Abstract

This paper describes a leaching-purifying-precipitation process to recover magnesium from serpentine acid-leaching solution and to synthesize high purity Mg(OH)2 and 4MgCO3·Mg(OH)2·4H2O. Fe, Al, and Cr in the leaching solution were removed using the oxidation precipitation method with active MgO as a precipitant and H2O2 as an oxidant. Ni, Co and Mn were removed by Na2S precipitation to obtain a pure MgSO4 solution. Mg2+ ions were first precipitated with NH3·H2O to synthesize Mg(OH)2, followed by NH4HCO3 precipitation to obtain 4MgCO3·Mg(OH)2·4H2O. A small part of MgSO4 coprecipitates with Mg(OH)2 to form MgSO4·5Mg(OH)2·3H2O. The Mg(OH)2 was aged with a diluted NaOH solution to remove the sulfur; the two-stage precipitation percentage of Mg is 96.3%. Mg(OH)2 has a purity of 98.48% with a sulfur content of 0.28%. This process provides a promising method for the high-efficiency recovery of Mg and the large-scale production of the high purity of Mg(OH)2 from the serpentine.

Keywords

• serpentine
• two-stage counter current leaching
• remove impurity
• MgSO₄·5Mg(OH)₂·3H₂O
• high purity Mg(OH)₂