Acta Crystallographica Section E (Jan 2011)

Bis{N,N-bis[(diphenylphosphanyl)methyl]aniline-κ2P,P′}copper(I) tetrafluoridoborate

  • Qing-Ling Ni,
  • Kai Ma,
  • Ting-Hong Huang,
  • Li-Li Huang,
  • Jing Shang

DOI
https://doi.org/10.1107/S160053681005186X
Journal volume & issue
Vol. 67, no. 1
pp. m96 – m96

Abstract

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In the cation of the title compound, [Cu(C32H29NP2)2]BF4, the CuI atom is four-coordinated in a distorted tetrahedral geometry by four P atoms from two N,N-bis[(diphenylphosphanyl)methyl]aniline ligands. In the crystal, the cations are linked by C—H...π interactions, forming chains along the a axis. Intramolecular C—H...N and intermolecular C—H...F hydrogen bonds are also observed.