CHIMIA (Nov 1985)

Isolation and Ionization of 1,1-Dihalogeno-1H-cyclopropa[a]-naphthalene

  • Paul Müller,
  • Huong Can Nguyen Thi

DOI
https://doi.org/10.2533/chimia.1985.362
Journal volume & issue
Vol. 39, no. 11

Abstract

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1,1-Difluoro- and 1,1-dichloro-1H-cyclopropa[a]naphthalenes (1a and 1b) are prepared via dehydrohalogenation of the appropriate brominated carbene adducts (2a and 2b, respectively) of 4-bromo-1,2-dihydronaphthalene. Upon dissolution of 1a in cold fluorosulfonic acid it furnishes the very short-lived cation 3; the latter is characterized by its 1H- and 19F-NMR spectra.