On the Response of Nascent Soot Nanostructure and Oxidative Reactivity to Photoflash Exposure
Wei Wang,
Dong Liu,
Yaoyao Ying,
Guannan Liu,
Ye Wu
Affiliations
Wei Wang
Key Laboratory of Thermal Control of Electronic Equipment, Ministry of Industry and Information Technology, Nanjing University of Science and Technology, Nanjing 210094, China
Dong Liu
Key Laboratory of Thermal Control of Electronic Equipment, Ministry of Industry and Information Technology, Nanjing University of Science and Technology, Nanjing 210094, China
Yaoyao Ying
Key Laboratory of Thermal Control of Electronic Equipment, Ministry of Industry and Information Technology, Nanjing University of Science and Technology, Nanjing 210094, China
Guannan Liu
Key Laboratory of Thermal Control of Electronic Equipment, Ministry of Industry and Information Technology, Nanjing University of Science and Technology, Nanjing 210094, China
Ye Wu
Key Laboratory of Thermal Control of Electronic Equipment, Ministry of Industry and Information Technology, Nanjing University of Science and Technology, Nanjing 210094, China
Soot particles are a kind of major pollutant from fuel combustion. To enrich the understanding of soot, this work focuses on investigating detailed influences of instantaneous external irradiation (conventional photoflash exposure) on nanostructure as well as oxidation reactivity of nascent soot particles. By detailed soot characterizations flash can reduce the mass of soot and soot nanostructure can be reconstructed substantially without burning. After flash, the degree of soot crystallization increases while the soot reactive rate decreases and the activation energy increases. In addition, nanostructure and oxidative reactivity of soot in air and Ar after flash are different due to their different thermal conductivities.
