Effects of Ethylene Propylene Diene Monomer (EPDM)-Based Polar Macromolecular Compatibilizers on the Low-Temperature Properties of Fluoroelastomer/EPDM Rubber Blends
Gen Liu,
Faxin Du,
Zhangjun Yao,
Guangzhao Li,
Wen Kuang,
Chongyu Zhu,
Yi Liu,
Honglin Chen,
Fumei Wang,
Ce Zhou,
Xueli Wei,
Wenyan Wang,
Rui Han
Affiliations
Gen Liu
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Faxin Du
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Zhangjun Yao
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Guangzhao Li
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Wen Kuang
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Chongyu Zhu
College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Fumei Wang
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Rui Han
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, China
Integrating rubber with superior low-temperature capabilities, such as ethylene propylene diene monomer (EPDM), is a strategic approach to bolster the low-temperature performance of fluoroelastomer (FKM). However, FKM and EPDM are thermodynamically incompatible. This work synthetized three EPDM-based polar macromolecular compatibilizers, epoxidized EPDM (EPDM-EP), 2,2-trifluoroethylamine-grafted epoxidized EPDM (EPDM-TF), and 2,4-difluorobenzylamine-grafted epoxidized EPDM (EPDM-DF), to enhance the compatibility between FKM and EPDM. These compatibilizers were subsequently incorporated into FKM/EPDM rubber blends. The results revealed that the glass transition temperature (Tg) of FKM/EPDM decreased by 1.3 °C, 2.68 °C, and 2.78 °C, respectively, upon the addition of 10 phr of EPDM-EP, EPDM-TF, or EPDM-DF. Moreover, the Tg of the two phases converged. The tensile strength, elongation at break, and tear strength of the FKM/EPDM rubber blends were also enhanced by the inclusion of these compatibilizers. Notably, EPDM-TF and EPDM-DF exhibited remarkable compatibilization effects due to an increase in polarity. This research not only sheds light on the potential for developing new compatibilizers but also paves the way for innovative applications of FKM and its derivatives.
