Communications Chemistry (Feb 2022)

Stabilization of gamma sulfur at room temperature to enable the use of carbonate electrolyte in Li-S batteries

  • Rahul Pai,
  • Arvinder Singh,
  • Maureen H. Tang,
  • Vibha Kalra

DOI
https://doi.org/10.1038/s42004-022-00626-2
Journal volume & issue
Vol. 5, no. 1
pp. 1 – 11

Abstract

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Lithium sulfur batteries are an emerging energy storage medium, but their stability in carbonate electrolyte remains hampered by side-reactions. Here, the authors show that as-produced monoclinic gamma-sulfur on activated carbon nanofibers converts to Li2S without the formation of intermediate polysulfides, therefore eliminating irreversible side reactions and improving cycling stability.