Molecules (Feb 2017)

An Easy Approach to Control β-Phase Formation in PFO Films for Optimized Emission Properties

  • Qi Zhang,
  • Lang Chi,
  • Gang Hai,
  • Yueting Fang,
  • Xiangchun Li,
  • Ruidong Xia,
  • Wei Huang,
  • Erdan Gu

DOI
https://doi.org/10.3390/molecules22020315
Journal volume & issue
Vol. 22, no. 2
p. 315

Abstract

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We demonstrate a novel approach to control β-phase content generated in poly(9,9-dioctylfluorene) (PFO) films. A very small amount of paraffin oil was used as the additive to the PFO solution in toluene. The β-phase fraction in the spin-coated PFO films can be modified from 0% to 20% simply by changing the volume percentage of paraffin oil in the mixed solution. Organic light emitting diodes (OLEDs) and amplified spontaneous emission (ASE) study confirmed low β-phase fraction promise better OLEDs device, while high β-phase fraction benefits ASE performance.

Keywords