Preparation of ATO-incorporated composite latex with tailored structure and controllable size for highly spectrum-selective applications

Abstract

We report a low-cost approach for fabricating highly transparent and infrared-shielding coatings by miniemulsion polymerization (MEP). Synthesis of ATO-incorporated composite latex with tailored structure was performed in a controlled manner by optimizing the process conditions via modified MEP. Antimony doped tin oxide (ATO) nanoparticles (NPs) were functionalized with 3-methacryloxy propyl trimethoxysilane (MPS) to improve the crosslinking between ATO NPs and polymers via MEP. ATO-incorporated composite MANs/poly(methyl methacrylate-co-butyl acrylate) (MANs/poly(MMA-co-BA)) latex was obtained by polymerizing ATO-incorporated composite latex with methyl methacrylate (MMA) and butyl acrylate (BA). Investigations revealed homogeneous distribution of ATO NPs in the composite (MANs/poly(MMA-co-BA)) latex owing to the better cross-linking with poly(MMA-co-BA). The spectral selectivity of the MANs/poly(MMA-co-BA) composite film was determined by ultraviolet-visible-near infrared (UV–Vis-NIR) spectroscopy. Interestingly, MANs/poly(MMA-co-BA) films exhibited stronger NIR-shielding properties by blocking up to 70% of NIR radiation in the range of 780–2500 nm while maintaining better visible light transparency of >80%. The results demonstrated that the prepared MANs/poly(MMA-co-BA) latex can be used as a spectrum-selective coating for next-generation transparent and IR-shielding materials. Keywords: Antimony doped tin oxide (ATO), Infrared shield, Miniemulsion polymerization, Reactive surfactant, Spectral selectivity