Acta Crystallographica Section E (Oct 2011)
1-Azido-N′-(phenylsulfonyl)methanimidamide
Abstract
In the title compound, C7H7N5O2S, the aromatic ring is oriented at dihedral angles of 79.46 (2) and 89.17 (2)°, respectively, with respect to the amino(azido)methyl and the S(6) six-membered ring motif generated by an intramolecular N—H...O interaction [N...O = 2.8901 (15) Å]. Intermolecular N—H...O hydrogen bonds [N...O = 2.9177 (15) and 2.9757 (15) Å] generate an infinite one-dimensional network along the base vector (010).