Synthesis and Spectroscopic Study of New 1<i>H</i>-1-Alkyl-6-methyl-7-nitroso-3-phenylpyrazolo[5,1-c][1,2,4]triazoles
Ion Burcă,
Valentin Badea,
Vasile-Nicolae Bercean,
Francisc Péter
Affiliations
Ion Burcă
Department of Applied Chemistry and Organic and Natural Compounds Engineering, Politehnica University Timisoara, Vasile Pârvan 6 Blvd., 300223 Timisoara, Romania
Valentin Badea
Department of Applied Chemistry and Organic and Natural Compounds Engineering, Politehnica University Timisoara, Vasile Pârvan 6 Blvd., 300223 Timisoara, Romania
Vasile-Nicolae Bercean
Department of Applied Chemistry and Organic and Natural Compounds Engineering, Politehnica University Timisoara, Vasile Pârvan 6 Blvd., 300223 Timisoara, Romania
Francisc Péter
Department of Applied Chemistry and Organic and Natural Compounds Engineering, Politehnica University Timisoara, Vasile Pârvan 6 Blvd., 300223 Timisoara, Romania
The nitrosation of 1H-1-alkyl-6-methyl-3-phenylpyrazolo[5,1-c][1,2,4]triazoles leads to new 1H-1-alkyl-6-methyl-7-nitroso-3-phenylpyrazolo[5,1-c][1,2,4] triazoles that react in acidic media, giving rise to 1H-1-alkyl-7-hydroxyimino-6-methyl-3-phenylpyrazolo[5,1-c][1,2,4]triazolium salts. These compounds were characterized by FT-IR, UV-Vis, 1H-NMR, 13C-NMR, and 15N-NMR spectroscopic techniques.
