Effect of Ultrasonic-Assisted Preparation of Powders on Synthesis of Rare Earth Zirconates

Abstract

The aim of the research was to determine the effect of sonochemical treatments on homogenization of powders as well as phase composition and thermal stability of sinters. The compounds were prepared from Eu2O3 and ZrO2 powders, weighed in the mass ratio 1:1. Initially ultrasound treatment was applied. 750-Watt ultrasonic processor VCX-750 equipped with sealed converter VC-334 and horn 630-0219 with the diameter of 13 mm (Sonics & Materials, Inc.) was used as a source of ultrasound. Applied ultrasound frequency was 20 kHz, power density was controlled in the range from 75 W/cm2 to 340 W/cm2. Investigated compounds were synthesized via solid-state reaction (SSR). The Differential Scanning Calorimetry (DSC) was used in order to investigate the effect of sonochemical treatment on the synthesis of prepared mixtures the powders particle size distribution was analyzed. Ultrasound treatment what wasn’t never been reported before.

Keywords

• pirochlore
• ultrasonic
• tbc