Molecules (May 2015)

1,3-Diphenylethenylcarbazolyl-Based Monomer for Cross-Linked Hole Transporting Layers

  • Maryte Daskeviciene,
  • Giedre Bubniene,
  • Tadas Malinauskas,
  • Vygintas Jankauskas,
  • Valentas Gaidelis,
  • Valdas Paulauskas,
  • Vytautas Getautis

DOI
https://doi.org/10.3390/molecules20059124
Journal volume & issue
Vol. 20, no. 5
pp. 9124 – 9138

Abstract

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A new cross-linkable monomer containing 1,3-diphenylethenylcarbazolyl-based hole-transporting moieties and four reactive epoxy groups, was prepared by a multistep synthesis route from 1,3-bis(2,2-diphenylethenyl)-9H-carbazol-2-ol and its application for the in situ formation of cross-linked hole transporting layers was investigated. A high concentration of flexible aliphatic epoxy chains ensures good solubility and makes this compound an attractive cross-linking agent. The synthesized compounds were characterized by various techniques, including differential scanning calorimetry, xerographic time of flight, and electron photoemission in air methods.

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