Corn Cobs’ Biochar as Green Host of Salt Hydrates for Enhancing the Water Sorption Kinetics in Thermochemical Heat Storage Systems

Abstract

Heat storage technologies are essential for increasing the use of solar energy in the household sector. Their development can be achieved by designing new storage materials; one way is to impregnate a porous matrix with hygroscopic salts. In this article, the possibility of using biochar-based composite sorbents to develop promising new heat storage materials for efficient thermal storage is explored. Biochar-based composites with defined salt loadings (5, 10, 15, and 20%) were produced by impregnating MgSO4 into a biochar matrix derived from corn cobs. The new materials demonstrated a high water sorption capacity of 0.24 g/g (20MgCC). After six successive charging-discharging cycles (dehydration/dehydration cycles), only a negligible variation of the heat released and the water uptake was measured, confirming the absence of deactivation of 20MgCC upon cycling. The new 20MgCC composite showed an energy storage density of 635 J/g (Tads = 30 °C and RH = 60%), higher than that of other composites containing a similar amount of hydrate salt. The macroporous nature of this biochar increases the available surface for salt deposition. During the hydration step, the water molecules effectively diffuse through a homogeneous layer of salt, as described by the intra-particle model applied in this work. The new efficient biochar-based composites open a low-carbon path for the production of sustainable thermal energy storage materials and applications.

Keywords

• thermochemical energy storage
• solid/gas sorption
• biochar
• salt hydrate
• material characterization