ChemistryOpen
(Jan 2023)
Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach
Dr. Seetharaman Manojveer,
Nitish K. Garg,
Zarif Gul,
Ayesha Kanwal,
Dr. Yogesh Goriya,
Dr. Magnus T. Johnson
Affiliations
Dr. Seetharaman Manojveer
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Nitish K. Garg
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Zarif Gul
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Ayesha Kanwal
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Dr. Yogesh Goriya
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
Dr. Magnus T. Johnson
Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden
DOI
https://doi.org/10.1002/open.202200245
Journal volume & issue
Vol. 12,
no. 1
Abstract
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Abstract A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstrated.
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