Controlling photophysical properties of ultrasmall conjugated polymer nanoparticles through polymer chain packing

Abstract

Synthesis of small conjugated polymer nanoparticles (Pdots) with bright and stable fluorescence is an active challenge. Here, the authors introduce a strategy to fabricate ultrasmall Pdots with high fluorescence intensity by using twisted, rather than planar, conjugated polymers, lending new insight into the molecular design of Pdots.