Data on the identification and characterization of by-products from N-Cbz-3-aminopropanal and t-BuOOH/H2O2 chemical reaction in chloroperoxidase-catalyzed oxidations
Gerard Masdeu,
Míriam Pérez-Trujillo,
Josep López-Santín,
Gregorio Álvaro
Affiliations
Gerard Masdeu
Bioprocess Engineering and Applied Biocatalysis Research Group, Departament d’Enginyeria Química, Biològica i Ambiental, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia, Spain
Míriam Pérez-Trujillo
Servei de Ressonància Magnètica Nuclear, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia, Spain
Josep López-Santín
Bioprocess Engineering and Applied Biocatalysis Research Group, Departament d’Enginyeria Química, Biològica i Ambiental, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia, Spain; Corresponding author. Tel.: +34 93 581 1018; fax: +34 93 581 2013.
Gregorio Álvaro
Bioprocess Engineering and Applied Biocatalysis Research Group, Departament d’Enginyeria Química, Biològica i Ambiental, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia, Spain
This data article is related to the subject of a publication in Process Biochemistry, entitled “Chloroperoxidase-catalyzed amino alcohol oxidation: Substrate specificity and novel strategy for the synthesis of N-Cbz-3-aminopropanal” (Masdeu et al., 2016) [1]. Here, the products of the chemical reaction involving the amino aldehyde (N-Cbz-3-aminopropanal) and peroxides (tert-butyl hydroperoxide and H2O2) are characterized by NMR. 1H and 13C NMR full characterization of the products was obtained based on 2D NMR, 1D selective NOESY and diffusion spectroscopy (DOSY) experiments. Keywords: N-Cbz-3-aminopropanal, Aldehyde-peroxide reaction, NMR identification
