Nano-Micro Letters (May 2024)

Branch-Chain-Rich Diisopropyl Ether with Steric Hindrance Facilitates Stable Cycling of Lithium Batteries at − 20 °C

  • Houzhen Li,
  • Yongchao Kang,
  • Wangran Wei,
  • Chuncheng Yan,
  • Xinrui Ma,
  • Hao Chen,
  • Yuanhua Sang,
  • Hong Liu,
  • Shuhua Wang

DOI
https://doi.org/10.1007/s40820-024-01419-z
Journal volume & issue
Vol. 16, no. 1
pp. 1 – 15

Abstract

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Highlights Branch chain-rich diisopropyl ether (DIPE) was selected as co-solvent of low-temperature electrolyte for lithium metal battery. The introduction of DIPE improved the disorder of electrolyte and the branch chains from DIPE exclude other solvents from the Li+ solvent sheath, thereby achieving a rapid desolvation process. The electrolyte guaranteed a uniform Li stripping and deposition during cycling at both room temperature and low temperature and ensured stable cycling performance for Li||LFP cells over 650 cycles at − 20 °C.

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