Electro-Fenton mineralization of real textile wastewater by micron-sized ZVI powder anode

Abstract

The diverse compositions and complex nature of the textile wastewater make it imperative to find an economical and suitable degradation pathway. The degradation of real textile wastewater on a novel heterogeneous electro-Fenton system was carried out with a composite anode of magnetically fixed micron ZVI coupling with a Ti/RuO2-IrO2 sheet. The influences of different variables such as mZVI dosage, H2O2 amount, applied voltage and pH value on both total organic carbon and chemical oxygen demand removal efficiencies and energy consumption were investigated. The optimized parameters were simultaneously verified by using electrochemical workstation Tafel curves and Nyquist plots. The optimal operating conditions for evaluating the wastewater treatment were H2O2 dosage of 0.10 mol·L−1, applied voltage of 5.0 V, mZVI amount of 1.0 g·L−1 and initial pH value of 3.0. The high TOC and COD removal efficiencies of 92.44 and 82.84% could be achieved simultaneously in 60 min, respectively. XRD, XPS and SEM-EDS were used to investigate the interaction between the pollutant and the mZVI. GC-MS analysis was performed on untreated and treated wastewater to determine the degradation of pollutants in dyeing wastewater during the electro-Fenton process and to effectively propose a suitable degradation mechanism for this system. HIGHLIGHTS A heterogeneous electro-Fenton process was performed on mZVI anode.; This study is performed on the real textile wastewater.; High COD and TOC removal efficiencies were achieved by the heterogeneous E-Fenton process.; The performance of electro-Fenton for contaminant removal was evaluated at different parameters.; The mechanisms were proposed based on the physiochemical and electrochemical properties of the anode.;

Keywords

• aops
• degradation
• electro-fenton process
• textile wastewater