Fabrication of ZnO-Carbon Dots Composite via Microcrystalline Cellulose for Enhanced Photocatalytic Hydrogen Production under Simulated Sunlight Irradiation
Xiangyu Li,
Wanquan Hu,
Shuo Qiao,
Yuexin Chang,
Longxiao Gu,
Yang Wang,
Hui-Liang Sun,
Yuan-Ru Guo
Affiliations
Xiangyu Li
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Wanquan Hu
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Shuo Qiao
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Yuexin Chang
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Longxiao Gu
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Yang Wang
Harbin Centre for Disease Control and Prevention (Harbin Centre for Health Examination), Harbin 150030, China
Hui-Liang Sun
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Yuan-Ru Guo
Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
The composite ZnO@CDs was prepared via the hydrothermal method. Microcrystalline cellulose (MCC) was used as the source of carbon dots (CDs). X-ray diffraction, Fourier transform infrared spectrometry, scanning electron microscopy, and transmission electron microscopy analyses were used to characterize the structure and morphology of ZnO@CDs. The prepared ZnO showed a flake morphology with the exposed plane of (001). The X-ray photoelectron spectroscopy and photoluminescence spectroscopy (PL) characterization showed that CDs can be produced by decomposition of MCC and then attached on the surface of ZnO. The photocatalytic properties of ZnO@CDs were investigated under simulated sunlight irradiation. The hydrogen production reached 1240 µmol·g-1 in 30 min, which was much higher than the bare ZnO. The mechanism for the enhanced catalytic property of ZnO@CDs was studied. A high hydrogen production rate (2480 µmol·g-1·h-1) in the short term would enable ZnO@CDs to work as an emergency power supply by hydrogen production and use for restoring electricity and wireless communication in complicated situations.
