(5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-Dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-Methylgymnodimine B)

Wendy Strangman; Matthew Anttila; Carmelo Tomas; Jeffrey L. C. Wright

doi:10.3390/M896

Molbank (Apr 2016)

(5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-Dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-Methylgymnodimine B)

Wendy Strangman,
Matthew Anttila,
Carmelo Tomas,
Jeffrey L. C. Wright

Affiliations

Wendy Strangman: UNC Wilmington, 5600 Marvin K. Moss Lane, Wilmington, NC 28409, USA
Matthew Anttila: UNC Wilmington, 5600 Marvin K. Moss Lane, Wilmington, NC 28409, USA
Carmelo Tomas: UNC Wilmington, 5600 Marvin K. Moss Lane, Wilmington, NC 28409, USA
Jeffrey L. C. Wright: UNC Wilmington, 5600 Marvin K. Moss Lane, Wilmington, NC 28409, USA

DOI: https://doi.org/10.3390/M896
Journal volume & issue: Vol. 2016, no. 2
p. M896

Abstract

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A new member of the gymnodimine class of spiroimine toxins has been isolated from a laboratory culture strain of Alexandrium ostenfeldii. Extensive one-dimensional (1D) and two-dimensional (2D) NMR data analysis was used to elucidate its structure as 12-methylgymnodimine B.

Published in Molbank

ISSN: 1422-8599 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: https://www.mdpi.com/journal/molbank

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