Acta Crystallographica Section E: Crystallographic Communications (Sep 2020)

Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris(4,5-dihydrofuran-2-yl)methylsilane and tris(4,5-dihydrofuran-2-yl)phenylsilane

  • Anna Krupp,
  • Eva Rebecca Barth,
  • Rana Seymen,
  • Carsten Strohmann

DOI
https://doi.org/10.1107/S2056989020011470
Journal volume & issue
Vol. 76, no. 9
pp. 1514 – 1519

Abstract

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The title compounds, C13H18O3Si (1) and C18H20O3Si (2), represent functionalizable dihydrofuranylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak intermolecular C—H...O hydrogen-bonding interactions (quantified by Hirshfeld surface analysis), leading to a two-dimensional supramolecular network for 1 and a one-dimensional supramolecular network for 2. The crystal structures of 1 and 2 were refined both on the basis of the independent atom model (IAM) and the Hirshfeld atom refinement (HAR) approach, and the results are comparatively discussed.

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