Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack

Abstract

Abstract Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and methods to predict the service life are needed. Here we propose a universal formula based on the dissolved amount of calcium ion to predict the deterioration rate of cement-based grout caused by acid deposition in the laboratory. The experimental results showed that the dissolved amount of calcium ion had a linear relationship with lnT and the pH value, with better accuracy when the pH value was greater than 3.0. This work maybe could provide a facile and quantitative method to help us predict the service life of cement-based grouting material under acid rain attack outdoors.

Keywords

• Cement
• Macrokinetics
• Reaction rate constant
• Acid rain
• Ca2+ ion