Frontiers in Chemistry (Apr 2020)
MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
Abstract
Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h−1 at 80°C. The presence of PVP was shown to play a positive role by increasing the hydrophilicity of the materials and enhancing the interface contact between the reactant molecules and the catalytic active sites.
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