Energies (Sep 2020)

Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications

  • Mukhtar Yeleuov,
  • Christopher Seidl,
  • Tolganay Temirgaliyeva,
  • Azamat Taurbekov,
  • Nicholay Prikhodko,
  • Bakytzhan Lesbayev,
  • Fail Sultanov,
  • Chingis Daulbayev,
  • Serik Kumekov

DOI
https://doi.org/10.3390/en13184943
Journal volume & issue
Vol. 13, no. 18
p. 4943

Abstract

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The renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibited a very high specific surface area (SSA) of 3292 m2 g−1. The surface morphology of the synthesized materials was studied using scanning and transmission electron microscopy (SEM, TEM). Furthermore, the AGC was modified with nickel hydroxide Ni(OH)2 through a simple chemical precipitation method. It was found that the most significant increase in capacitance could be reached with Ni(OH)2 loadings of around 9 wt.%. The measured specific capacitance of the pure AGC supercapacitor electrodes was 236 F g−1, whereas electrodes from the material modified with 9 wt.% Ni(OH)2 showed a specific capacitance of up to 300 F g−1 at a current density of 50 mA g−1. The increase in specific capacitance achieved due to chemical modification was, therefore 27%.

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