On the Question of the Problems of Statistical Calculations of the Conducting Crystals Thermodynamic and Kinetic Properties.

Abstract

This paper presents an elementary model of a crystal and its thermodynamic equilibrium state. It was shownthat the thermodynamic characteristics of the crystal at this state are described by the Gibbs grand thermodynamicpotential. If the crystal is removed away from the equilibrium state, then in this state it will be described by theset of kinetic properties, and these properties are statistically calculated with the use of the non-equilibrium Gibbsgrand thermodynamic potential. Crystals’ thermodynamic and kinetic properties have analytical dependence onthe current carriers dispersion law and chemical potential of these carriers. In this work, it was shown that thedetermination of the dispersion law and chemical potential – these are complicated problems of statistical andkinetic theories of crystals’ properties.

Keywords

• потенціал гіббса
• закон дисперсії
• хімічний потенціал
• дрейфова сила