AIP Advances (Mar 2012)

Enhanced upconversion fluorescence of Er3+:ZrO2 nanocrystals induced by phase transformation

  • L. Liu,
  • Y. J. Chen,
  • X. L. Zhang,
  • Y. X. Wang,
  • X. R. Zhang,
  • Y. L. Song

DOI
https://doi.org/10.1063/1.3676601
Journal volume & issue
Vol. 2, no. 1
pp. 012102 – 012102-7

Abstract

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In this letter, we demonstrate for the first time a growth of monoclinic phase ZrO2 nanocrytals based on a sol-gel method, compared to the ordinary sol-gel procedure, our method decreases the synthesized temperature from ∼1000 °C to ∼800 °C. In addition, it is found that Er3+ in monoclinic phase ZrO2 nanocrystals have greatly enhanced upconversion emissions under infrared LD excitation due to its lower environmental symmetry.