Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system

Wan-Min Cheng; Rui Shang; Yao Fu

doi:10.1038/s41467-018-07694-w

Nature Communications (Dec 2018)

Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system

Wan-Min Cheng,
Rui Shang,
Yao Fu

Affiliations

Wan-Min Cheng: Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, Department of Chemistry, University of Science and Technology of China
Rui Shang: Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, Department of Chemistry, University of Science and Technology of China
Yao Fu: Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, Department of Chemistry, University of Science and Technology of China

DOI: https://doi.org/10.1038/s41467-018-07694-w
Journal volume & issue: Vol. 9, no. 1
pp. 1 – 9

Abstract

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Production of alkenes through decarboxyolefination of carboxylates is a synthetically useful process. Here, the authors report a palladium/dual ligand-enabled decarboxylative desaturation reaction under mild irradiation conditions and apply it to the synthesis of Chondriamide A and C.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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