AIP Advances (Sep 2012)

Sizeable magnetic circular dichroism of artificially precipitated Co clusters in amorphous carbon

  • H. S. Hsu,
  • W. Y. Su,
  • P. C. Chien,
  • S. T. Kuo,
  • S. J. Sun,
  • P. Y. Chuang,
  • C. H. Lee,
  • G. H. Hwang

DOI
https://doi.org/10.1063/1.4747509
Journal volume & issue
Vol. 2, no. 3
pp. 032142 – 032142-6

Abstract

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This study examines sizeable magnetic circular dichroism (MCD) in Co(20%)-doped amorphous carbon (a-C) films. While as-grown films exhibit a non-detectable MCD signal, films that undergo rapid thermal annealing (RTA) at 600°C in a vacuum yield broad MCD spectra with a large amplitude of ∼3.9 × 104 deg/cm in saturation field 0.78 T at the σ-σ* gap transition (∼5.5 eV). In such films after RTA, the metastable Co-C bonding is decomposed and suitable Co nanoparticles/a-C interfaces are thus formed. Our results indicate that the large change in MCD is contributed from Co nanoparticles and associated with the spin-dependent electronic structure at the Co/a-C interfaces.