Spectrally Stable Blue Light-Emitting Diodes Based on All-Inorganic Halide Perovskite Films
Huidan Zhang,
Ying Su,
Xulan Xue,
Qinghui Zeng,
Yifang Sun,
Kai Zhu,
Weiguang Ye,
Wenyu Ji,
Xiangyang Leng
Affiliations
Huidan Zhang
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Dong_Nanhu Road 3888, Changchun 130033, China
Ying Su
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Dong_Nanhu Road 3888, Changchun 130033, China
Xulan Xue
Key Lab of Physics and Technology for Advanced Batteries (Ministry of Education), Department of Physics, Jilin University, Changchun 130012, China
Qinghui Zeng
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Dong_Nanhu Road 3888, Changchun 130033, China
Yifang Sun
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Dong_Nanhu Road 3888, Changchun 130033, China
Kai Zhu
Changchun University of Chinese Medicine, Changchun 130017, China
Weiguang Ye
State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Dong_Nanhu Road 3888, Changchun 130033, China
Wenyu Ji
Key Lab of Physics and Technology for Advanced Batteries (Ministry of Education), Department of Physics, Jilin University, Changchun 130012, China
Xiangyang Leng
Changchun University of Chinese Medicine, Changchun 130017, China
Substantial progress has been made in perovskite light-emitting diodes (PeLEDs), but the fabrication of high-performance blue PeLEDs still remains a challenge due to its low efficiency, spectral instability and short operational lifetime. How to produce an efficient and stable blue PeLED is the key to realizing the application of PeLEDs in full-color displays. We herein report a blue PeLED usint the ligand-assisted reprecipitation method, in which phenylethylammonium bromide (PEABr) was used as ligands, and chloroform was used as anti-solvent to prepare blue perovskite nanocrystal films. By increasing the PEABr content from 40% to 100% (The ratio of x% PEABr refers to the molar ratio between PEABr and PbBr2), the film quality is highly improved, and the emission exhibits a blue shift. Introducing a poly(9-vinylcarbazole) (PVK) hole transport layer into the device, the PVK layer can not only achieve efficient hole injection, but can also isolate the PEDOT: PSS layer to inhibit the non-radiative recombination of metal halide luminescence layer, reduce surface ion defects and successfully inhibit halide atom migration. Finally, the PeLED presents a stable electroluminescence under different driving voltages without any red shift.
