Synthesis and Structure of a Coordination Polymer of Ni(II) with 2-(4-Bromophenoxy)acetohydrazide
Оlena Martsynko,
Mariia Nesterkina,
Оlena Finik,
Kyrylo Tsymbaliuk,
Viktoriya Dyakonenko,
Svitlana Shishkina,
Iryna Kravchenko
Affiliations
Оlena Martsynko
Department of Inorganic Chemistry and Chemical Education, Odesa I.I. Mechnikov National University, 65082 Odessa, Ukraine
Mariia Nesterkina
Helmholtz Institute for Pharmaceutical Research Saarland (HIPS)-Helmholtz Centre for Infection Research (HZI), Campus Building E 8.1, 66123 Saarbrücken, Germany
Оlena Finik
Limited Liability Company “INSPECTORAT UKRAINE”, 65044 Odessa, Ukraine
Kyrylo Tsymbaliuk
Department of Inorganic Chemistry and Chemical Education, Odesa I.I. Mechnikov National University, 65082 Odessa, Ukraine
Viktoriya Dyakonenko
State Scientific Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 61001 Kharkov, Ukraine
Svitlana Shishkina
State Scientific Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 61001 Kharkov, Ukraine
Iryna Kravchenko
Helmholtz Institute for Pharmaceutical Research Saarland (HIPS)-Helmholtz Centre for Infection Research (HZI), Campus Building E 8.1, 66123 Saarbrücken, Germany
The coordination compound [NiCl2L(2-PrOH)]n (where L is 2-(4-bromophenoxy)acetohydrazide; 2-PrOH is isopropanol) was obtained for the first time. The complex was characterized by means of elemental analyses, molar conductance, thermogravimetric analysis, IR spectroscopy, and single crystal X-ray diffraction analysis. It was determined that the coordination compound exhibits a polymeric structure. The complexing agent is six-coordinated, and its distorted octahedron forms due to the bidentate coordination of 2-(4-bromophenoxy)acetohydrazide through the carbonyl oxygen atom and the amine nitrogen. The oxygen of the molecule of isopropanol, the chlorine atom, and two chlorine atoms serve as bridges between two metal atoms.
