Mono-, Bis-, and Tris-Chelate Zn(II) Complexes with Imidazo[1,5-<i>a</i>]pyridine: Luminescence and Structural Dependence

Abstract

New mono-, bis-, and tris-chelate Zn(II) complexes have been synthesized starting from different Zn(II) salts and employing a fluorescent 1,3-substituted-imidazo[1,5-a]pyridine as a chelating ligand. The products have been characterized by single-crystal X-ray diffraction; mass spectrometry; and vibrational spectroscopy. The optical properties have been investigated to compare the performances of mono-, bis-, and tris-chelate forms. The collected data (in the solid state and in solution) elucidate an important modification of the ligand conformation upon metal coordination; which is responsible for a notable increase in the optical performance. An intense modification of the emission quantum yield along the series in the solid state is observed comparing mono-, bis-, and tris-chelate adducts; independently from the anionic ligand introduced by ionic exchange.

Keywords

• imidazo[1,5-<i>a</i>]pyridine
• luminescence
• fluorescence
• zinc complex
• quantum yield
• Stokes shift