Scientific Reports (Nov 2022)

Dry etching of ternary metal carbide TiAlC via surface modification using floating wire-assisted vapor plasma

  • Thi-Thuy-Nga Nguyen,
  • Kazunori Shinoda,
  • Hirotaka Hamamura,
  • Kenji Maeda,
  • Kenetsu Yokogawa,
  • Masaru Izawa,
  • Kenji Ishikawa,
  • Masaru Hori

DOI
https://doi.org/10.1038/s41598-022-24949-1
Journal volume & issue
Vol. 12, no. 1
pp. 1 – 13

Abstract

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Abstract Dry etching of ternary metal carbides TiAlC has been first developed by transferring from wet etching to dry etching using a floating wire (FW)-assisted Ar/ammonium hydroxide vapor plasma. FW-assisted non-halogen vapor plasma generated at medium pressure can produce high-density reactive radicals (NH, H, and OH) for TiAlC surface modifications such as hydrogenation and methylamination. A proposed mechanism for dry etching of TiAlC is considered with the formation of the volatile products from the modified layer.