Inhibiting effect of a composite formulation of kinetic and thermodynamic inhibitors for gas hydrate formation in high water cut oil–water emulsion

Abstract

Abstract In oil and gas exploitation and transportation, it is essential to avoid hydrate blockage in the wellbores and pipelines. Using kinetic inhibitors in composite with thermodynamic inhibitors can reduce the operational expenditure for oil and gas pipelines under high water content conditions. The phase equilibria of pure water natural gas system, oil–water natural gas system, and oil–water monoethylene glycol (MEG) natural gas system were first investigated by experiments and combined with software predictions in this study. The results showed that both mineral oil and MEG shifted the phase equilibrium of the system to high‐pressure and low‐temperature directions. The oil phase increased the effective temperature range of the compounding inhibitor. Then the hydrate inhibition performance and natural gas hydrate generation characteristics of the composite formulation of Luvicap 55w and MEG in oil–water emulsions and natural gas mixtures were investigated. With the increased subcooling, the induction time decreased sharply, and the gas consumption increased. The induction time increased with increasing MEG concentration, which verified the synergistic effect of MEG in oil–water emulsion for Luvicap 55w. The hydrate generation characteristics did not change much with increasing Luvicap concentration at the same temperature. In contrast, the hydrate induction time rose from 142.8 to >3500 min as the MEG concentration increased from 10 to 20 wt%.

Keywords

• hydrate blockage
• induction time
• kinetics hydrate inhibitor
• oil–water emulsion
• phase equilibrium
• thermodynamic hydrate inhibitor