Acta Crystallographica Section E (Feb 2008)

Bis[methyl 2-(2-pyridylmethylidene)hydrazinecarbodithioato]zinc(II)

  • Yue-Peng Cai,
  • Xiao-Ming Lin,
  • Jian-Qiao Chen,
  • Zheng-Yuan Zhou,
  • Xiu-Xia Zhou

DOI
https://doi.org/10.1107/S1600536807068493
Journal volume & issue
Vol. 64, no. 2
pp. m328 – m329

Abstract

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In the title compound, [Zn(C8H8N3S2)2], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiolate S atom; the coordination geometry is distorted octahedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The molecules are linked by C—H...S hydrogen bonds, forming a three-dimensional network structure.