Preparation and properties of modified ammonium polyphosphate synergistic with tris(2-hydroxyethyl) isocynurate for flame-retardant LDPE

Abstract

UF-SiAPP was prepared by modifying ammonium polyphosphate with the urea formaldehyde resin (UF), tetraethylorthosilicate (TEOS), and vinyltriethoxysilane (A-151). Moreover, a new intumescent flame retardant (IFR) used for low density polyethylene (LDPE) flame retardant was obtained by mixing UF-SiAPP with tris(2-hydroxyethyl) isocynurate (THEIC). The structure, morphology, and mechanical properties of flame retardants and LDPE composites were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, TG, and universal material testing machines. Furthermore, the flame-retardant properties of LDPE composites were comprehensively investigated by limiting oxygen index (LOI), UL-94, and cone calorimetry tests. The results show that UF-SiAPP exhibits excellent hydrophobic properties and good compatibility with LDPE after being modified by UF, TEOS, and A-151. And the flame-retardant properties of LDPE composites are significantly improved by adding IFR-containing UF-SiAPP. Especially, the LDPE composites attained the LOI value of 30.5% and reached the V-0 level after introducing 20.0 wt% UF-SiAPP and 10.0 wt% THEIC. And the tensile strength reached 13.55 MPa, which was 10.33% higher than that of LDPE/IFR with UF-APP and 13.21% higher than that of LDPE/IFR without THEIC in the same proportion. The smoke density tests demonstrate that the addition of UF-SiAPP not only effectively improves the residual carbon content and thermal stability of LDPE composites but also significantly reduces smoke emissions.

Keywords

• ammonium polyphosphate
• tris(2-hydroxyethyl) isocynurate
• modification
• synergy
• flame-retardant ldpe