Toxics (Sep 2022)

Study on Tritium and Iodine Species Transport through Porous Granite: A Non-Sorption Effect by Anion Exclusion

  • Yunfeng Shi,
  • Song Yang,
  • Wenjie Chen,
  • Weijia Xiong,
  • Aiming Zhang,
  • Zhixiang Yu,
  • Bing Lian,
  • Chuan-Pin Lee

DOI
https://doi.org/10.3390/toxics10090540
Journal volume & issue
Vol. 10, no. 9
p. 540

Abstract

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The safety of deep geological repositories is important in the disposal of high-level radioactive waste (HLW). In this study, advection–dispersion experiments were designed to build a transport model through a calibration/validation process, and the transport behavior of tritiated water (HTO) and various iodine species (iodide: I− and iodate: IO3−) was studied on a dynamic compacted granite column. Breakthrough curves (BTCs) were plotted under various flow rates (1–5 mL/min). BTCs showed that the non-sorption effect by anion exclusion was observed only in I− transport because the retardation factor (R) of I− was lower than that of HTO (R = 1). Moreover, equilibrium and nonequilibrium transport models were used and compared to identify the mobile/immobile zones in the compacted granite column. The anion exclusion effect was influenced by the immobile zones in the column. The non-sorption effect by anion exclusion (R − at 5.0 ± 0.2 mL/min flow rate, and a relatively higher Coulomb’s repulsive force may be caused by the smaller hydration radius of I−(3.31 Å) than that of IO3−(3.74 Å).

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