Geochemical partitioning of Cu and Zn in Pelabuhanratu Bay sediment

Abstract

Activities such as fishing ports and power plants on the coast of Pelabuhanratu Bay have recently developed and hence, their input of metal-containing waste may influence the seawater quality of the bay as the fishing grounds. This study aimed to determine the potential sources (i.e., anthropogenic and natural) and pollution status in sediments. Sediment samples were collected once at 10 stations in the bay using a Van Veen grab. The geochemical partitioning of non-residual and residual phases of metals was used to assess the anthropogenic and natural sources, respectively. The status of metal contamination was evaluated by determining the geo-accumulation index (Igeo), contamination factor (CF), and pollution load index (PLI). Generally, Cu was dominant in residual fractions ranging 62.79-81.24%, while Zn ranged 39.56-66.02%. This suggests that Cu and Zn in Pelabuhanratu Bay are naturally sourced. Furthermore, the average geo-accumulation index of Cu was categorized as unpolluted (-0.86), and Zn was lightly polluted (0.87). The CF of Cu indicates the uncontaminated category (0.85), whereas Zn indicates a moderate contamination category (CF = 1.54). The pollution level (PLI) in Pelabuhanratu Bay is generally lightly polluted (PLI 1,135).