Acta Crystallographica Section E (May 2011)

rac-12,14-Dicyclopropyl-5,8,13,18,21-pentaoxapentacyclo[13.8.0.02,11.04,9.017,22]tricosa-1(15),2(11),3,9(10),16,22(23)-hexaene

  • Viktor A. Tafeenko,
  • Leonid A. Aslanov,
  • Nikolay A. Puretskiy,
  • Aleksander N. Fedotov,
  • Sergei S. Mochalov

DOI
https://doi.org/10.1107/S1600536811013961
Journal volume & issue
Vol. 67, no. 5
pp. o1180 – o1180

Abstract

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The molecule of the title compound, C24H24O5, has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the ethylene group C atoms deviating by 0.472 (5) and −0.248 (6) Å from the plane defined by the remaining ring atoms.