Acta Crystallographica Section E (May 2012)

Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate

  • Zhi-Quan Pan,
  • Ming Liu,
  • Jia-Wei Mao,
  • Hui-Ting Song

DOI
https://doi.org/10.1107/S1600536812017941
Journal volume & issue
Vol. 68, no. 5
pp. m694 – m695

Abstract

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In the title solvated molecular salt, [CuCl(C28H30N4)]ClO4·CH3OH, the Cu2+ ion is coordinated by the N,N′,N′′,N′′′-tetradentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN4Cl coordination geometry with the Cl− ion in the basal position. In the crystal, the solvent molecules and anions are linked by weak O—H...O hydrogen bonding.