Mathematical modeling of the effect of spacers on mass transfer in electromembrane systems

Abstract

The transfer of ions near ion-exchange membranes causes concentration polarization, which significantly complicates mass transfer in electromembrane systems. Spacers are used to neutralize the effect of concentration polarization and increase mass transfer. Spacers reduce the thickness of the boundary layer by increasing the mixing depth of the solution and creating a normal component of convective transport; ions can reach membranes faster, and the current increases, from a hydrodynamic point of view. However, spacers significantly increase the hydrodynamic resistance and consequently the cost of pumping the solution. For the first time, the main regularities of the transfer of salt ions in the desalination channel of an electrodialysis apparatus with spacers of various shapes and arrangements are determined, taking into account electroconvection, in overlimiting current modes. Namely, it is shown, using the current-voltage characteristic, that spacers of different shapes and locations are optimal at different stages of the desalination process. The paper presents the results of mathematical and simulation modeling of the salt ion transport process in electromembrane systems with spacers in overlimiting current modes. 2D direct numerical simulation was carried out for the coupled system of the NernstPlanckPoisson and NavierStokes equations without fitting parameters. The finite element method was used in combination with the method of successive approximations and segregation to solve boundary value problems for systems of nonlinear differential equations with partial derivatives. The novelty of the method lies in the fact that after discretization in time, the problem on each time layer is split into hydrodynamic and electrochemical problems, each of which is solved by the method of successive approximations until a complete mutual agreement.

Keywords

• electromembrane system
• spacers
• mass transfer
• ion transfer
• mathematical model