IUCrData (Dec 2024)

trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)

  • Fatima Setifi,
  • Zouaoui Setifi,
  • Uwe Böhme,
  • Mohammad Hadi Al-Douh,
  • Achouak Satour

DOI
https://doi.org/10.1107/S2414314624012197
Journal volume & issue
Vol. 9, no. 12
p. x241219

Abstract

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The title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetracyano-2-methoxypropenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic b axis and parallel to (110).

Keywords