Improvement of dye-sensitized solar cells' performance via co-sensitization of new azo thiazole organic dyes with ruthenium (II) based N-719 dye

Abstract

Three novel azo thiazole organic dyes, NA-1–3, have been synthesized and utilized as co-sensitizers in dye-sensitized solar cells (DSSCs). These co-sensitizers were designed with a thiazole ring π-bridge that mediates between the diazo (–N = N–) functional group and carboxylic acid anchoring unit. They possess a rod-like molecular structure and exhibit strong UV–vis absorption near 600 nm. Co-sensitization studies were also conducted with the ruthenium complex N719. The co-sensitized DSSCs showed enhanced short-circuit and open-circuit photocurrents (Jsc) and voltages (Voc), resulting in more efficient photovoltaic performance compared to N719 (PCE 7.25%). Electrochemical impedance spectroscopy (EIS) and incident photon to current efficiency (IPCE) were employed to investigate the underlying reasons for these improvements. It was found that co-sensitization effectively reduced electron recombination, resulting in a higher Voc without compromising photocurrent loss.

Keywords

• Azo thiazole organic dyes
• Co-sensitization
• Chemical synthesis
• Dye-sensitized solar cells
• Photoconversion efficiency